You can align vector points by selecting the nodes and using the align tools as usual. Press Enter when you have a vector object selected to enter Editing Mode. This will give you access to the node editing tools and alignment.Distribute horizontally or vertically. You will sometimes get a sub-pixel warning. It is best practice NOT to align to sub-pixels.Align multiple objects to the artboard by holding the Alt key.Align a single object to the artboard.